Search results for "Vadose zone"
showing 10 items of 13 documents
Comparative assessment of a foam-based method for ISCO of coal tar contaminated unsaturated soils
2019
Abstract In situ delivery of liquid reagents in vadose zone is limited by gravity and soil anisotropy. A new foam-based delivery method of persulfate (PS) solutions in unsaturated soils was previously shown to overcome these limitations. The goal of this paper is to demonstrate the efficiency of this method regarding contaminant removal. Hence, the comparative oxidation of 200 mg.kg−1 coal tar artificially contaminated soils with thermally activated PS was carried out after PS-delivery using foam, surfactant solution and pure water. The foam-based method was compared in unfavorable conditions to the reference methods. Especially, in the latter, soil and oxidant solutions were thoroughly mix…
Field testing parameter sensitivity of the two-term infiltration equation using differentiated linearization
2003
Knowledge of soil hydraulic conductivity in the vadose zone is important in many agronomic, engineering and environmental areas. Transient tension infiltrometer experiments can be used to estimate the hydraulic conductivity, K0, corresponding to a given pressure head by the single-test (TST) method that uses the coefficients C1 and C2 of the two-term infiltration equation. The “Differentiated Linearization” (DL) method has been proposed to estimate these coefficients when a layer of contact material is used for the experiment. A field test of the DL and TST methods was conducted on a sandy loam and a clay soil. Eliminating the early-time influence of the contact layer was easy when the sorp…
Comparative assessment of a foam-based oxidative treatment of hydrocarbon-contaminated unsaturated and anisotropic soils.
2019
Abstract In situ delivery of liquid reagents in vadose zone is limited by soil anisotropy and gravity. The enhanced delivery of persulfate (PS) as oxidant, using a new foam-based method (F-PS) was compared at bench-scale to traditional water-based (W-PS) and surfactant solution-based (S-PS) deliveries. The goal was to distribute PS uniformly in coal tar-contaminated unsaturated and anisotropic soils, both in terms of permeability and contamination. Water was the less efficiently delivered fluid because of the hydrophobicity of the contaminated soils. Surfactant enhanced PS-distribution into contaminated zones by reducing interfacial tension and inverting soil wettability. Regardless of coal…
A new foam-based method for the (bio)degradation of hydrocarbons in contaminated vadose zone
2020
International audience; An innovative foam-based method for Fenton reagents (FR) and bacteria delivery was assessed for the in situ remediation of a petroleum hydrocarbon-contaminated unsaturated zone. The surfactant foam was first injected, then reagent solutions were delivered and propagated through the network of foam lamellae with a piston-like effect. Bench-scale experiments demonstrated the feasibility of the various treatments with hydrocarbon (HC) removal efficiencies as high as 96 %. Compared to the direct injection of FR solutions, the foam-based method led to larger radii of influence and more isotropic reagents delivery, whereas it did not show any detrimental effect regarding H…
Shear-thinning fluids for gravity and anisotropy mitigation during soil remediation in the vadose zone
2018
Abstract Surfactant foam has been proposed as an effective treatment fluid for in situ environmental remediation of soils. In the vadose zone, it could improve treatment homogeneity, but its use remains challenging. To better understand and predict foam formation and propagation in vadose zone, we studied them in 24 soils with wide range of properties (including permeability: 2 10−12 to 3.3 10−9 m2). Foam rheology showed to be complex and mostly influenced by soil permeability and grading. Below 2 10−11 m2, foam propagation velocity was not influenced by permeability. Conversely, slight shear thinning to Newtonian behavior was observed for higher permeabilities. Benefits for remediation in …
Effects of initialization on response of a fully-distributed hydrologic model
2008
Summary Knowledge of initial conditions is very important to correctly model the basin response at the storm event scale. Of particular interest is the influence of topography and soil type on the principal hydrologic variables and runoff generation mechanisms as a function of antecedent wetness conditions. This study addresses the influence of initial states on the short-term hydrologic response and characterizes the effects of topography and soils on the dissipation of the influence of the initialization conditions. Two case studies are considered: a synthetic two-dimensional planar hillslope with various assumed slope magnitudes and soil types; and a real basin (∼800 km2) with actual lan…
Upper pleistocene interstratal piping-cave speleogenesis: The seso cave system (central pyrenees, northern spain)
2015
The Seso Cave System (SCS, South Central Pyrenees, Northeastern Spain) develops in poorly soluble marly interstratum between limestone beds of Eocene age. We propose an innovative and singular pseudokarstic speleogenetic model under vadose conditions based on cave morphological evidence, physicochemical and mineralogical characteristics of the Eocene marly host rock, U-Th dating of cave deposits, and local geological and geomorphological information. Eocene marls are shown to be sensitive to dispersion processes supported by their high clay content and the high concentration of sodium and low electrical conductivity in the seepage water. Runoff inside the cave results from water that infilt…
Discussion of "Hydraulic Model of Transition of Transient to Steady Flows in the Vadose Zone" by Yaguo Zhang, Tonglu Li, Wei Shen, and Yu Wang
2020
The authors wrote an interesting article dealing with a simple hydraulic model to illustrate the transition mechanism of transient to steady flows in the vadose zone. The soil behavior is described by a set of nine vertically aligned cylinders, each opened at the top and with a small outlet at the bottom. The water level dynamic of each cylinder, associated with an intermittent constant rainfall applied to the top cylinder, C0, was analyzed and numerical simulations were performed. The only objective of this discussion is to show that results similar to those proposed by the authors could be obtained by using the recently introduced Richards equation analytical solution, under gravity-drive…
Shallow urban aquifers under hyper-recharge equatorial conditions and strong anthropogenic constrains. Implications in terms of groundwater resources…
2021
Abstract Humid equatorial regions are recognized as the least documented in term of hydrogeological functioning of aquifers despite the fact that they house a lot of developing countries and that groundwater is often the main water resource. Regarding this aspect, a study was conducted in sub-Saharan Africa, focusing on the Mio-Pliocene aquifer in Douala megacity (Cameroon) which is the rainiest city in West-Africa (about 4000 mm/year) with one of the greatest demographic growth rate of the African continent. Firstly, groundwater recharge rate has been calculated through water balance and Water Table Fluctuation methods. Results show that the aquifer is characterized by a high recharge of 6…
Characterization and modeling of water movement and salts transfer in a semi-arid region of Tunisia (Bou Hajla, Kairouan) – Salinization risk of soil…
2012
Abstract The semi-arid region of Bou Hajla (Kairouan – Central Tunisia) is exposed to the risk of soils and aquifers salinization. A characterization of water movement through the use of TDR probes installed at up to 4 m in depth, and of salts transfer by soil sampling was conducted to highlight this risk. At the same time, climatic parameters were monitored. The results were gathered over the period of approximately 1 year (June 12, 2006 to May 08, 2007). Water infiltration and evaporation, occurred at within distinct materials: two zero flux planes at 1 and 3 m, and a clay-silt layer at 2 m where the soil water content and electrical conductivity is highly varied. Saline profiles show sal…